nHibarnate is currently unfortunately not supported by our .NET Agent. One option you can do in those cases is to do manual instrumentation with the public agent API.
One thing we plan is to have direct ADO.NET support - this is a good issue to follow for that. I believe that it'd also help with nHibernate, because if I'm not mistaken it uses ADO.NET internally - at least in standard scenarios. But I'm not 100% sure here, so this is something which should be verified.
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